Thursday, April 21, 2011

Czochralski process : to get hyper pure silicon (99.99999.....%)............



  • The Czochralski process is a method of crystal growth used to obtain single crystals of semiconductors (e.g. silicon, germanium and gallium arsenide), metals (e.g. palladium, platinum, silver, gold), salts, and synthetic gemstones. The process is named after Polish scientist Jan Czochralski, who discovered the method in 1916 while investigating the crystallization rates of metals.
  • The most important application may be the growth of large cylindrical ingots, or boules, of single crystal silicon. Other semiconductors, such as gallium arsenide, can also be grown by this method, although lower defect densities in this case can be obtained using variants of the Bridgman-Stockbarger technique.
  • High-purity, semiconductor-grade silicon (only a few parts per million of impurities) is melted down in a crucible, which is usually made of quartz. Dopant impurity atoms such as boron or phosphorus can be added to the molten intrinsic silicon in precise amounts in order to dope the silicon, thus changing it into n-type or p-type extrinsic silicon. This influences the electronic properties of the silicon. A precisely oriented seed crystal, mounted on a rod, is dipped into the molten silicon. The seed crystal's rod is very slowly pulled upwards and rotated at the same time. By precisely controlling the temperature gradients, rate of pulling and speed of rotation, it is possible to extract a large, single-crystal, cylindrical ingot from the melt. Occurrence of unwanted instabilities in the melt can be avoided by investigating and visualizing the temperature and velocity fields during the crystal growth process.This process is normally performed in an inert atmosphere, such as argon, and in an inert chamber, such as quartz.
  • Video for the process is here.......

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